Palladium-catalyzed Vinylation Of Organic Halides Pdf Download

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1999;38:24112413….J…Later..reports..by..the..same..group31..and..Kikukawa..et..al.32..demonstrated..that..these..transformations..actually..occur..by..a..Heck-type..process,..i.e…2001;3:18971900…J…

Denmark..SE,..Sweis..RF…Peyroux…E,…Berthiol…F,…Doucet…H,…Santelli…M….Bull…..1973;46:15051508.14…..A…wide…range…of…aryl…bromides,…including…both…electron-rich…(entries…1…and…2)…and…electron-deficient…(entries…3–7)…substrates,…are…successfully…vinylated…and…a…range…of…functional…groups…are…tolerated…including…dimethylamino,…nitro,…cyano…and…formyl…groups….This….feature….has….allowed….a….wide….array….of….activation….protocols….and….reaction….conditions….to….be….developed…..Whereas..each..of..the..three..activators..does..facilitate..the..coupling..with..aryl..iodides,..silver..oxide..does..not..work..in..reactions..that..employ..aryl..bromides…Metal-Catalyzed…Cross-Coupling…Reactions….Modern..Styrenic..Polymers:..Polystyrenes..and..Styrenic..Copolymers…

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